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Kinetics and mechanism of the thermal rearrangement of some (chloromethyl)silanes

✍ Scribed by Clarke, Michael P.; Damrauer, Robert.; Davidson, Iain M. T.; Simon, Roger.


Book ID
126145112
Publisher
American Chemical Society
Year
1989
Tongue
English
Weight
413 KB
Volume
8
Category
Article
ISSN
0276-7333

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Kinetics and mechanism of the silane dec
✍ C. G. Newman; H. E. O'neal; M. A. Ring; F. Leska; N. Shipley πŸ“‚ Article πŸ“… 1979 πŸ› John Wiley and Sons 🌐 English βš– 871 KB

The homogeneous gas-phase decomposition kinetics of silane has been investigated using the single-pulse shock tube comparative rate technique (T = 1035-1184Β°K, P ~d = 4000 Torr). The initial reaction of the decomposition SiH4 ! + SiHz + H2 is a unimolecular process in its pressure fall-off regime w