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Kinetics and Mechanism of the Spontaneous Decompositions of Some Peroxoacids, Hydrogen Peroxide and t -Butyl Hydroperoxide

✍ Scribed by Koubek, E.; Haggett, M. L.; Battaglia, C. J.; Ibne-Rasa, Khairat M.; Pyun, H. Y.; Edwards, J. O.


Book ID
120408275
Publisher
American Chemical Society
Year
1963
Tongue
English
Weight
848 KB
Volume
85
Category
Article
ISSN
0002-7863

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Oscillatory kinetics and mechanism of th
✍ MihΓ‘ly T. Beck; IstvΓ‘n P. Nagy; Gabriella SzΓ©kely πŸ“‚ Article πŸ“… 1991 πŸ› John Wiley and Sons 🌐 English βš– 590 KB

Oscillatory change of pH occurs during the chromate-catalyzed decomposition of hydrogen peroxide in a weakly acidic medium at elevated temperature and at high initial concentration of hydrogen peroxide. In a closed system, there are only two or three periods, but sustained oscillation occurs in a CS