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Kinetics and mechanism of the reduction of hexacyanoferrate(III) by (ethylenediaminetetraacetato)hydroxocobaltate(II)

✍ Scribed by Reagor, Barbara T.; Huchital, Daniel H.

Book ID: 120208516
Publisher: American Chemical Society
Year: 1982
Tongue: English
Weight: 338 KB
Volume: 21
Category: Article
ISSN: 0020-1669
DOI: 10.1021/ic00132a047

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## Abstract The oxidation of halotoluenes by hexacyanoferrate(III) in aqueous acetic acid containing perchloric acid (0.5__M__) at 50°C gave the corresponding aldehyde as the major product, and a small amount of polymeric material. The order with respect to each of the reactants—substrate, oxidant,