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Kinetics and mechanism of the reactions of [Pt(terpy)H2O]2+ with thiols in acidic aqueous solution. Synthesis and crystal structure of [Pt(terpy)(tu)](ClO4)2 (tu = thiourea)

✍ Scribed by Bugarčič, Živadin D.; Liehr, Günter; van Eldik, Rudi


Book ID
120525699
Publisher
The Royal Society of Chemistry
Year
2002
Tongue
English
Weight
187 KB
Volume
14
Category
Article
ISSN
1472-7773

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In aqueous solution, bis(nucleoside) complexes formed by the reaction of cis-[Pt(NH3)2(H2O)2]2+ with an excess of either adenosine (ado) or a mixture of adenosine and guanosine (guo) undergo a slow N7--> N1 linkage isomerisation in the adenine moiety. The isomerisation probably involves the breaking