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Kinetics and mechanism of the reactions of bis(cyclopentadienyl carbonyl nickel) with alkynes

โœ Scribed by P.L. Stanghellini; R. Rossetti; O. Gambino; G. Cetini


Book ID
114041657
Publisher
Elsevier Science
Year
1973
Tongue
English
Weight
569 KB
Volume
7
Category
Article
ISSN
0020-1693

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Under nickel(O) mediation, trimethylsilyl(iso)cyanide serves as both a useful synhydrocyanating agent and a carbonylating agent for alkynes. Metallacyclopentadienes have often been proposed as essential intermediates in the cyclotrimerization of alkynes into benzene derivatives.' Specifically in the