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Kinetics and mechanism of the reaction of thionyl chloride with substituted acetophenone semicarbazones. The synthesis of 1,2,3-thiadiazoles

โœ Scribed by Butler, Richard N.; O'Donoghue, Denis A.

Book ID
111862809
Publisher
Royal Society of Chemistry
Year
1982
Weight
508 KB
Volume
0
Category
Article
ISSN
1472-7781

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Mechanism of the abnormal reaction of th
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โœ Arnold J. Krubsack; Tatsuo Higa ๐Ÿ“‚ Article ๐Ÿ“… 1968 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 231 KB

In 8 recent paper (3) the authors suggested that the abnormal reaction of thionyl chloride with 4-nitro-2,5-dimethoxyphenylacetic acid to give a sulfenyl chloride proceeded by means of a mechanism which involved Dxidation of a benzylic position. Although