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Kinetics and mechanism of the reaction of fluorine atoms with trifluoroacetic acid

✍ Scribed by E.S. Vasiliev; V.D. Knyazev; E.S. Savelieva; I.I. Morozov

Book ID
113554979
Publisher
Elsevier Science
Year
2011
Tongue
English
Weight
248 KB
Volume
512
Category
Article
ISSN
0009-2614

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Kinetics and mechanisms for the reaction
Kinetics and mechanisms for the reaction of hydroxyl radicals with trifluoroacetic acid under atmospheric conditions
✍ SinΓ©ad Carr; Jack J. Treacy; Howard W. Sidebottom; Richenda K. Connell; Carlos E πŸ“‚ Article πŸ“… 1994 πŸ› Elsevier Science 🌐 English βš– 619 KB

The rate constant for the gas-phase reaction of the hydroxyl radical with trifluoroacetic acid has been determined over the temperature range 283-323 K using a relative rate technique. The results provide a value of k( OH+CF,C(O)OH) = 2.O~lO-\*~exp(-l46~500/T)cm~molecule~'s-'basedonk(OH+C~H,)=7.8~lO