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Kinetics and mechanism of the reaction of allyl chloride with trichlorosilane catalyzed by carbon-supported platinum

✍ Scribed by Bogdan Marciniec; Hieronim Maciejewski; Wojciech Duczmal; Ryszard Fiedorow; Dariusz Kityński


Publisher
John Wiley and Sons
Year
2003
Tongue
English
Weight
168 KB
Volume
17
Category
Article
ISSN
0268-2605

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✍ D. Martin Davies; Michael E. Deary; Kieran Quill; Robert A. Smith 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 English ⚖ 258 KB 👁 2 views

## Abstract The kinetics of the oxidation of substituted phenyl methyl sulfides by hydrogen peroxide in borate/boric acid buffers were investigated as a function of pH, total peroxide concentration, and total boron concentration. Second‐order rate constants at 25 °C for the reaction of methyl 4‐nit