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Kinetics and mechanism of the reaction of a quasi-aromatic copper(II) complex, [Cu(PnAO)-6H]0, with formaldehyde

✍ Scribed by Zhong-Ming Wang; Hua-Kuan Lin; Zhi-Fen Zhou; Shou-Rong Zhu; Yun-Ti Chen; R. Kent Murmann

Book ID: 110246737
Publisher: Springer
Year: 2000
Tongue: English
Weight: 134 KB
Volume: 25
Category: Article
ISSN: 0340-4285
DOI: 10.1023/a:1007045910691

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Ninhydrin has been found to react with Cu(glycine)+ and Cu(alanine)+ in the ratio of 1:l. The kinetic studies of the reaction were carried out at different concentrations of the reactants at 80°C (pH = 5.0). The reaction proceeds through the formation of a ternary labile complex of ninhydrin with Cu