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Kinetics and mechanism of the pyrolysis of 1,3-cyclohexadiene. Thermal source of cyclohexadeienyl radicals and hydrogen atoms. Addition of hydrogen atoms to benzene and toluene

✍ Scribed by Benson, Sidney W.; Shaw, Robert.


Book ID
126231078
Publisher
American Chemical Society
Year
1967
Tongue
English
Weight
426 KB
Volume
89
Category
Article
ISSN
0002-7863

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Addition of hot hydrogen atoms to 1-bute
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## Abstract The reaction of hot hydrogen atoms originating from 253.7‐ and 228.8‐nm photolyses of hydrogen sulfide with 1‐butene was investigated. Of the hydrogen atoms undergoing addition a substantial part undergoes it in a first collision (37 and 48% at 253.7 and 228.8 nm, respectively) yielding