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Kinetics and Mechanism of the Pudovik Reaction in the Azomethine Series: II.1Hydrolysis and Catalysis in the Reaction of Dialkyl Phosphites with Benzalaniline

✍ Scribed by A. A. Sobanov; A. V. Zolotukhin; V. I. Galkin; O. A. Mostovaya; R. A. Cherkasov; A. N. Pudovik

Book ID
111560434
Publisher
Springer
Year
2003
Tongue
English
Weight
71 KB
Volume
73
Category
Article
ISSN
1070-3632

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Alrstract--Trialkyl phosphites react with cyanoisopropylperoxyl radicals, generated by thermolysis of azobis(isobutyronitrile) in the presence of oxygen, to give the corresponding phosphates with rate constants of the order of 103 M -~ sec -~ at 65Β°C. Phenyl phosphites are oxidized also. A small amo