Kinetics and mechanism of the oxidation of primary aliphatic alcohols by pyridinium bromochromate
β Scribed by P Aparna; Seema Kothari; Kalyan K Banerji
- Book ID
- 112926509
- Publisher
- Indian Academy of Sciences,Royal Society of Chemistry
- Year
- 1995
- Tongue
- English
- Weight
- 391 KB
- Volume
- 107
- Category
- Article
- ISSN
- 0253-4134
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
The kinetics of oxidation of four vicinal diols, four nonvicinal diols, and one of their monoethers by pyridinium bromochromate (PBC) have been studied in dimethyl sulfoxide. The main product of oxidation is the corresponding hydroxyaldehyde. The reaction is first-order with respect to each the diol
## Abstract The oxidative deoximination of several aldoβ and ketoβoximes by pyridinium bromochromate (PBC), in dimethylsulfoxide, exhibited a firstβorder dependence on both the reductant (oxime) and the oxidant (PBC). The oxidation of ketoximes is slower than that of aldoximes. The rates of oxidati
The oxidation of some aliphatic alcohols by quinolinium fluorochromate (QFC) in dimethyl sulfoxide leads to the formation of corresponding carbonyl compounds. The reaction is first order with respect to QFC. The reaction exhibited Michaelis-Menten type kinetics with respect to the alcohol. The react