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Kinetics and mechanism of the oxidation of primary aliphatic alcohols by pyridinium bromochromate

✍ Scribed by P Aparna; Seema Kothari; Kalyan K Banerji


Book ID
112926509
Publisher
Indian Academy of Sciences,Royal Society of Chemistry
Year
1995
Tongue
English
Weight
391 KB
Volume
107
Category
Article
ISSN
0253-4134

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πŸ“œ SIMILAR VOLUMES


Kinetics and mechanism of the oxidation
✍ P. Surya Chandra Rao; Deepa Suri; Seema Kothari; Kalyan K. Banerji πŸ“‚ Article πŸ“… 1998 πŸ› John Wiley and Sons 🌐 English βš– 122 KB πŸ‘ 2 views

The kinetics of oxidation of four vicinal diols, four nonvicinal diols, and one of their monoethers by pyridinium bromochromate (PBC) have been studied in dimethyl sulfoxide. The main product of oxidation is the corresponding hydroxyaldehyde. The reaction is first-order with respect to each the diol

Kinetics and mechanism of the oxidative
✍ Pradeep K. Sharma πŸ“‚ Article πŸ“… 2006 πŸ› John Wiley and Sons 🌐 English βš– 80 KB

## Abstract The oxidative deoximination of several aldo‐ and keto‐oximes by pyridinium bromochromate (PBC), in dimethylsulfoxide, exhibited a first‐order dependence on both the reductant (oxime) and the oxidant (PBC). The oxidation of ketoximes is slower than that of aldoximes. The rates of oxidati

Kinetics and mechanism of the oxidation
✍ K. Choudhary; P. K. Sharma; K. K. Banerji πŸ“‚ Article πŸ“… 1999 πŸ› John Wiley and Sons 🌐 English βš– 134 KB πŸ‘ 2 views

The oxidation of some aliphatic alcohols by quinolinium fluorochromate (QFC) in dimethyl sulfoxide leads to the formation of corresponding carbonyl compounds. The reaction is first order with respect to QFC. The reaction exhibited Michaelis-Menten type kinetics with respect to the alcohol. The react