Kinetics and mechanism of the oxidation of organic sulphides by 2,2′-bipyridinium chlorochromate
✍ Scribed by Shashi Vyas; Pradeep K. Sharma
- Book ID
- 110638254
- Publisher
- Indian Academy of Sciences,Royal Society of Chemistry
- Year
- 2002
- Tongue
- English
- Weight
- 87 KB
- Volume
- 114
- Category
- Article
- ISSN
- 0253-4134
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## Abstract The oxidation of glycolic, lactic, malic, and a few substituted mandelic acids by 2,2′‐bipyridinium chlorochromate (BPCC) in dimethylsulphoxide leads to the formation of corresponding oxoacids. The reaction is first order each in BPCC and the hydroxy acids. The reaction is catalyzed by
## Abstract The oxidation of organic sulfides by morpholinium chlorochromate (MCC) resulted in the formation of the corresponding sulfoxides. The reaction is first order with respect to both MCC and the sulfide. The reaction is catalyzed by toluene‐__p__‐sulfonic acid (TsOH). The oxidation was stud