Kinetics and mechanism of the oxidation of ketones with permanganate ions
✍ Scribed by Jáky, Miklós; Szammer, János; Simon-Trompler, Edit
- Book ID
- 121356148
- Publisher
- Royal Society of Chemistry
- Year
- 2000
- Tongue
- English
- Weight
- 129 KB
- Volume
- 7
- Category
- Article
- ISSN
- 1472-779X
- DOI
- 10.1039/B000116N
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The kinetics of the permanganate-hypophosphite redox reaction has been studied over a wide range of pH by using a stopped-flow technique. It has been found that the reaction leads to the formation of phosphite and orthophosphate, and that the molar ratio of the final products depends on pH. The prop
## Abstract The kinetics and mechanism of permanganate ion oxidation of acetylacetone (Acac) was studied in acidic and alkaline media. The rate constants for keto, enol, and enolate anions were determined and discussed. Delocalization of the π‐electrons of the double bond by conjugation results in