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Kinetics and mechanism of the oxidation of iron(II) by thiocyanatopentaamminecobalt(III) ions. Comparisons with related systems

✍ Scribed by Fay, Douglas P.; Sutin, Norman


Book ID
120563191
Publisher
American Chemical Society
Year
1970
Tongue
English
Weight
380 KB
Volume
9
Category
Article
ISSN
0020-1669

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The oxidation of ethylenediamine by diperiodatoargentate (III) ion has been studied by stopped-flow spectrophotometry. Kinetics of this reaction involves two steps. The first step is the complexation of silver (III) with the substrate and is over in about 10 ms. This is followed by a redox reaction