Kinetics and Mechanism of the NCCO + NO Reaction
β Scribed by Feng, Wenhui; Hershberger, John F.
- Book ID
- 126965817
- Publisher
- American Chemical Society
- Year
- 2010
- Tongue
- English
- Weight
- 445 KB
- Volume
- 114
- Category
- Article
- ISSN
- 1089-5639
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## Abstract The kinetics of the reaction of CH~3~O with NO and the branching ratio for HCHO product formation, obtained as Ξ~HCHO~ = (Rate of HCHO formation) / (Rate of CH~3~O decay), have been studied using a discharge flow reactor. Laser induced fluorescence has been used to monitor the decay of
The reaction of CF, with NO, was studied at 296 2 2 K using two different absolute techniques Absolute rate constants of ( I 6 ? 0.3) X lo-" and ( 2 1-03+07) X lo-" cm3 molecule-' s-' were derived by IR fluorescence and UV absorption spectroscopy, respectively The reaction proceeds via two reaction