Kinetics and mechanism of the interaction of thioglycolic acid with [(H2O)(tap)2RuORu(tap)2(H2O)]2+ion at physiological pH
β Scribed by Alak Kumar Ghosh
- Publisher
- Springer
- Year
- 2006
- Tongue
- English
- Weight
- 352 KB
- Volume
- 31
- Category
- Article
- ISSN
- 0340-4285
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## Abstract The interaction of the title complex with selected amino acids such as glycine (L^1^H), lβvaline (L^2^H), and lβleucine (L^3^H) has been studied spectrophotometrically in aqueous medium as a function of [substrate complex], [ligand], and temperature. The reaction has been monitored at 6
lL11c coefficrents for coll1s1on~1 removal of Ott D) by SLY atnlosplrertc gases have been measured by momtormg the appearance of O(3P) followng photolvtlc productlon of O(' D) The measured values, x"hI 2 SJ, m units of IO-" cm3 molccule-' s-l arc k-0, = ?? 8 5 :! 3, k~~ = 2 52 ? 0.25, k-co, = 10 4 +