The anodic dissolution of nickel in HCl-DMSO solutions containing different supporting electrolytes has been studied between 2@45"C. The electrodissolution and electrodeposition are predominantly activated electrode processes. At high anodic potentials and in the presence of perchlorate ions at high
Kinetics and mechanism of the hydrogen-evolution reaction on mercury in HCl-dimethylsulphoxide solutions
✍ Scribed by D. Posadas; A.J. Arvía
- Book ID
- 107748609
- Publisher
- Elsevier Science
- Year
- 1973
- Tongue
- English
- Weight
- 467 KB
- Volume
- 18
- Category
- Article
- ISSN
- 0013-4686
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The electrochemical reduction of the solvated hydrogen ion dissolved in DMSO as HCl was investigated from 25 to 45"C, at different concentrations and ionic strength. Stationary and nonstationary techniques were employed to obtain the kinetic parameters. The results were interpreted with a reaction s
The kinetics of hydrogen discharge in solutions of HCXDMSO is investigated within 10e3-1 N HCI concentrations, in the presence of KCIO, as supporting electrolyte. The cathodic slope is O-120V/dccade for all solutions. The electrochemical reaction order with respect to the hydrogen ion concentration