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Kinetics and mechanism of the formation of formazans by diazonium ion attack on hydrazones

✍ Scribed by Hegarty, A. F.; Scott, Francis Leslie

Book ID
120202114
Publisher
American Chemical Society
Year
1967
Tongue
English
Weight
976 KB
Volume
32
Category
Article
ISSN
0022-3263

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Kinetics and mechanism of the oxidation
Kinetics and mechanism of the oxidation of acetylacetone by permanganate ion
✍ MiklΓ³s JΓ‘ky; JΓ‘nos Szammer; Edit Simon-Trompler πŸ“‚ Article πŸ“… 2006 πŸ› John Wiley and Sons 🌐 English βš– 131 KB πŸ‘ 2 views

## Abstract The kinetics and mechanism of permanganate ion oxidation of acetylacetone (Acac) was studied in acidic and alkaline media. The rate constants for keto, enol, and enolate anions were determined and discussed. Delocalization of the π‐electrons of the double bond by conjugation results in