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Kinetics and mechanism of the formation and breakdown of the hydroperoxide in the course of oxidation of polystyrene

โœ Scribed by V.M Gol'dberg; V.N Yesenin; G.Ye Zaikov


Book ID
116048184
Publisher
Elsevier Science
Year
1986
Weight
369 KB
Volume
28
Category
Article
ISSN
0032-3950

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The oxidation of polystyrene initiated by the photodecomposition of 2,2'-azoisobutyronitrile at A > 300 nm was studied at 25ยฐC in chlorobenzene solution. The order of the reaction is approximately unity with respect to AIBN concentration and to the light intensity. The effects of concentration and m