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Kinetics and mechanism of the decomposition of mannich bases

โœ Scribed by V. M. Belikov; Yu. N. Belokon'; M. M. Dolgaya; N. S. Martinkova

Book ID
112435528
Publisher
Springer
Year
1967
Tongue
English
Weight
60 KB
Volume
16
Category
Article
ISSN
1573-9171

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The homogeneous gas-phase thermal decomposition kinetics of germane have been measured in a single-pulse shock tube between 950 and 1060 K at pressures around 4000 torr. The initial decomposition is GeH4 -GeH2 + H2 in its pressure-dependent regime, with log k ~~~~( 4 m ) = 13.83 f 0.78 -50,750 f 357