Kinetics and mechanism of the decomposition of CS2, OCS, and SCl2in a radiofrequency pulse discharge
โ Scribed by John E. Nicholas; Christopher A. Amodio
- Publisher
- Springer
- Year
- 1982
- Tongue
- English
- Weight
- 402 KB
- Volume
- 2
- Category
- Article
- ISSN
- 0272-4324
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๐ SIMILAR VOLUMES
The homogeneous gas-phase thermal decomposition kinetics of germane have been measured in a single-pulse shock tube between 950 and 1060 K at pressures around 4000 torr. The initial decomposition is GeH4 -GeH2 + H2 in its pressure-dependent regime, with log k ~~~~( 4 m ) = 13.83 f 0.78 -50,750 f 357
The homogeneous gas-phase decomposition kinetics of silane has been investigated using the single-pulse shock tube comparative rate technique (T = 1035-1184ยฐK, P ~d = 4000 Torr). The initial reaction of the decomposition SiH4 ! + SiHz + H2 is a unimolecular process in its pressure fall-off regime w
The pyrolysis of 2,2-dichloro-l , 1 ,I-trifluoroethane was studied over the temperature range of 112(tI26OoK at total reflected shock pressures from -2800 to 3100 torr. Below 1260"K, the decomposition leads to three reaction products which were identified as CF&FCI, CF&FH, and CF3CC13. The results a