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Kinetics and mechanism of the Co(ii)-assisted oxidation of thioureas by dioxygen

✍ Scribed by Kudrik, Evgeny V.; Theodoridis, Alexander; van Eldik, Rudi; Makarov, Sergei V.

Book ID
120199235
Publisher
Royal Society of Chemistry
Year
2005
Tongue
English
Weight
300 KB
Volume
6
Category
Article
ISSN
1477-9226

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Kinetics and mechanism of the oxidation
Kinetics and mechanism of the oxidation of thiourea by chlorine dioxide
✍ Gyula RΓ‘bai; Robert T. Wang; Kenneth Kustin πŸ“‚ Article πŸ“… 1993 πŸ› John Wiley and Sons 🌐 English βš– 602 KB

The stoichiometry and kinetics of the oxidation of thiourea (SC(NH2)z) by chlorine dioxide (ClOz) have been studied by uv-vis spectrophotometry using conventional and stopped-flow mixing techniques at 25.0 ? O.l"C, pH 0.3-4.8. In high acid and initial 10 : 1 molar ratio of thiourea to chlorine dioxi