Kinetics and mechanism of the base hydrolysis of thecis-chlorobis(ethylenediamme)(benzimidazole)cobalt(III) cation
β Scribed by Robert W. Hay; Paul R. Norman
- Publisher
- Springer
- Year
- 1981
- Tongue
- English
- Weight
- 405 KB
- Volume
- 6
- Category
- Article
- ISSN
- 0340-4285
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π SIMILAR VOLUMES
The alkaline hydrolysis of cisand rrans-diacetatobis(l,2-propanediamine)cobalt(III) cations appears to follow a substitution nucleophilic unimolecular conjugate base mechanism. In these cations, the acetate ligands are replaced by hydroxide ion in a stepwise manner. Both isomers undergo complete hy
## Abstract Rate constants for the hydrolysis (__k__~h~) of six different amines in __transβ__[Co((BA)~2~en)(amine)~2~]ClO~4~ complexes (amine = aniline 1a, paraβtoluidine 1b, benzylamine 1c (primary amines), pyrrolidine 2a, piperidine 2b, morpholine 2c (secondary amines), and (BA)~2~en = Bisbenzoy