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Kinetics and mechanism of substitution reactions of complexes—XII: Solvolytic aquation of some cis-chloro-amino-bis-ethylenediamino-Co(III)-complexes

✍ Scribed by J. Zsakó; Cs. Várhelyi; D. Dobocan

Book ID
118907442
Publisher
Elsevier Science
Year
1969
Weight
421 KB
Volume
31
Category
Article
ISSN
0022-1902

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The kinetics of aquation and racemizatio
The kinetics of aquation and racemization of some cis- chloro-, hydroxo-, and aquabis(ethylenediamine)(amine)cobalt(III) complexes
✍ D. R. Fenemor; D. A. House 📂 Article 📅 1976 🏛 John Wiley and Sons 🌐 English ⚖ 482 KB

Aquation rates for cis-CoCl(en)2(A)2+ (A = 3,5-lutidine, imidazole, N-methylimidazole, benzimidazole) have been determined by halide release titration in 1 .O M HNOz at 50-80°C. Kinetic parameters are (in the above order of A) 1O7k29s (sec-I), 7.4, 5.7, 1.3, 9.7; E, (kJ/mole), 103, 101, 130, 112; lo