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Kinetics and mechanism of selective hydroxylation of benzene catalysed by vanadium substituted heteropolymolybdates

✍ Scribed by Nirupa A Alekar; V Indira; S.B Halligudi; D Srinivas; S Gopinathan; C Gopinathan

Publisher
Elsevier Science
Year
2000
Tongue
English
Weight
178 KB
Volume
164
Category
Article
ISSN
1381-1169

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Functional action of Keggin-type mono-vanadium(V)-substituted heteropolymolybdate as a single species on catalytic hydroxylation of benzene in the presence of hydrogen peroxide
✍ Kenji Nomiya; Kazunori Yagishita; Yukihiro Nemoto; Tada-aki Kamataki πŸ“‚ Article πŸ“… 1997 πŸ› Elsevier Science 🌐 English βš– 988 KB

Benzene hydroxylation in the presence of hydrogen peroxide has been studied using tetrabutylammonium salts of three types of mono-vanadium(V)-substituted heteropolyanions (HPA) as catalyst precursors: (i) [PMo, ,V0,,14-(PMo, , V, l), which has been first prepared herein and identified as a single sp