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Kinetics and mechanism of rhodium(III) catalysed oxidation of polyhydric alcohols by acidified potassium bromate

✍ Scribed by Sheila Srivastava


Book ID
110243976
Publisher
Springer
Year
1999
Tongue
English
Weight
72 KB
Volume
24
Category
Article
ISSN
0340-4285

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Kinetics and mechanism of cerium(IV) oxi
✍ Laxman V. Nimbalkar; Anant M. Chavan; Gavisiddappa S. Gokavi πŸ“‚ Article πŸ“… 1998 πŸ› John Wiley and Sons 🌐 English βš– 115 KB πŸ‘ 2 views

The cerium(IV) oxidation of isobutanol, isoamyl alcohol isopropyl alcohol, and secondary butanol catalysed by chromium(III) was studied in sulphuric and perchloric acid mixture at 30 Β°C. The reaction was found to proceed with the formation of a chromium(IV) intermediate followed by its complexation