Kinetics and mechanism of reduction of sperm-whale metmyoglobin by dithionite ion
โ Scribed by Marylin Itzkowitz; Albert Haim
- Book ID
- 104105853
- Publisher
- Elsevier Science
- Year
- 1978
- Weight
- 663 KB
- Volume
- 9
- Category
- Article
- ISSN
- 0006-3061
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## Abstract The kinetics and mechanism by which monochloramine is reduced by hydroxylamine in aqueous solution over the pH range of 5โ8 are reported. The reaction proceeds via two different mechanisms depending upon whether the hydroxylamine is protonated or unprotonated. When the hydroxylamine is
The reaction of 2,6-dichlorophenolindophenol (DCPI) and dithionites is studied kinetically by applying the stopped-flow technique. Reaction rate constants are given for the pH range 1.30-6.80. The reaction was found to follow first-order kinetics with respect to each of the reactants. For pH 3.97,5.