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Kinetics and mechanism of reduction of gold(III) complexes by dimethyl sulfide

โœ Scribed by Ericson, Anna; Elding, Lars I.; Elmroth, Sofi K. C.

Book ID
118208426
Publisher
The Royal Society of Chemistry
Year
1997
Tongue
English
Weight
433 KB
Volume
7
Category
Article
ISSN
1472-7773

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The pyrolysis of dimethyl sulfide, kinet
The pyrolysis of dimethyl sulfide, kinetics and mechanism
โœ Lilian G. S. Shum; Sidney W. Benson ๐Ÿ“‚ Article ๐Ÿ“… 1985 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 581 KB

The kinetics of the gas phase pyrolysis of dimethyl sulfide (DMS) was studied in a static system a t 681-723 K by monitoring total pressure-time behavior. Analysis showed the pressure increase to follow DMS loss. The reaction follows two concurrent paths: ## Me2S C2H4 + H2S --% CH, + CHzS with a