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Kinetics and mechanism of reduction of a nickel(IV) oxime-imine complex by Co(edta)2-. Stereospecific synthesis of a stereoselective oxidant

โœ Scribed by Lappin, A. Graham; Laranjeira, Mauro C. M.; Peacock, Robert D.


Book ID
127346170
Publisher
American Chemical Society
Year
1983
Tongue
English
Weight
752 KB
Volume
22
Category
Article
ISSN
0020-1669

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Kinetics and mechanism of the oxidation
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The kinetics of the oxidation of formate, oxalate, and malonate by [Ni III (L 1 )] 2ฯฉ (where HL 1 ฯญ 15-amino-3-methyl-4,7,10,13-tetraazapentadec-3-en-2-one oxime) were carried out over the regions pH 3.0 -5. 75, 2.80 -5.50, and 2.50 -7.58, respectively, at constant ionic strength and temperature 40ะŠ