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Kinetics and mechanism of reactions of water-soluble ferriporphyrins. 2. Reduction by ascorbic acid

✍ Scribed by Harris, Francis L.; Toppen, David L.

Book ID
121473107
Publisher
American Chemical Society
Year
1978
Tongue
English
Weight
556 KB
Volume
17
Category
Article
ISSN
0020-1669

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The kinetics of the oxidation of ascorbic acid by diaquatetrakis (2,2'-bipyridine)-p-oxo diruthenium(III) in aqueous HC104 were investigated. The dependence of the second order rate constant k2 on [H +] is given by k2 = a + b[H+] -1, indicating that both the undissociated form and the monoanion of a