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Kinetics and mechanism of reactions of the drug tiopronin with platinum(IV) complexes

✍ Scribed by Huo, Shuying; Shi, Hongmei; Liu, Dongzhi; Shen, Shigang; Zhang, Jiong; Song, Changying; Shi, Tiesheng

Book ID
121997821
Publisher
Elsevier Science
Year
2013
Tongue
English
Weight
713 KB
Volume
125
Category
Article
ISSN
0162-0134

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Rates and mechanisms for halide anation
Rates and mechanisms for halide anation reactions of platinum(IV) complexes
✍ L.I. Elding; L. Gustafson πŸ“‚ Article πŸ“… 1977 πŸ› Elsevier Science 🌐 English βš– 736 KB

The bromide anation of tr-PtCl&H,O-has been studied at 25 "Cand the chloride anations of tr-PtCl,-BrH,O-and PtBrSHzO-at 50 "C, These reactions proceed via halide assisted mechanisms, compatible with the experimental rate laws: -d [tr-PtCl&H,O-] /dt = 0.43 [Br-] \* [ tr-PtClJBrH20-] s-' M-\* -d[tr-Pt