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Kinetics and mechanism of radical polymerization of methylmethacrylate usingp-acetylbenzylidene triphenylarsonium ylide (p-ABTAY) as an initiator

✍ Scribed by A. K. Srivastava; Neeta Daniel

Publisher: Springer
Year: 2000
Tongue: English
Weight: 297 KB
Volume: 7
Category: Article
ISSN: 1022-9760
DOI: 10.1007/s10965-006-0116-x

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## Abstract The free‐radical copolymerization of 4‐vinyl pyridine (4‐VP) with methyl acrylate (MA) initiated by __p__‐acetylbenzylidene triphenylarsonium ylide at 60 ± 0.1°C with dioxane as an inert solvent yielded random copolymers. The kinetic equation was __R__~__p__~ ∝ [Ylide]^0.83^[4‐VP]^0.33^