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Kinetics and mechanism of pressure reduction of nickel(II) with hydrogen from aqueous acetate solutions containing bismuth(III)

✍ Scribed by Jerzy Wódka; Witold Charewicz; Eugeniusz Gaska

Book ID
113311621
Publisher
Elsevier Science
Year
1991
Tongue
English
Weight
706 KB
Volume
27
Category
Article
ISSN
0304-386X

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Kinetics and mechanism of the reductions
Kinetics and mechanism of the reductions of azido- and isothiocyanatopentacyanocobaltate(III) by ruthenium(II) ammine species in aqueous solution
✍ Adedayo B. Adegboro; J.Folorunso Ojo; Olusegun Olubuyide; Oluyemisi T. Sheyin 📂 Article 📅 1987 🏛 Elsevier Science 🌐 English ⚖ 432 KB

The reductions of azido-and isothiocyanato-pentacyanocobaltate(II1) by hexaammine-and aquapentaammineruthenium(I1) have been investigated in aqueous solution at I = 0.20 mol dmm3 (LiCl) and the values at 25 "C of the rate constants (dm3 mol-' s-l) are ky = 1.71 and kNCs = 0.8 1 for the Ru(NH~)~~+ re