Kinetics and Mechanism of Platinum−Thallium Bond Formation: The Binuclear [(CN) 5 Pt−Tl(CN)] - and the Trinuclear [(CN) 5 Pt−Tl−Pt(CN) 5 ] 3- Complex
✍ Scribed by Nagy, Péter; Tóth, Imre; Fábián, István; Maliarik, Mikhail; Glaser, Julius
- Book ID
- 120390126
- Publisher
- American Chemical Society
- Year
- 2004
- Tongue
- English
- Weight
- 114 KB
- Volume
- 43
- Category
- Article
- ISSN
- 0020-1669
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📜 SIMILAR VOLUMES
The crystal and molecular structure of a polycrystalline powder with a metal-metal bond and the composition TlPt(CN)5 has been determined by combining results from X-ray powder diffraction (XRD), extended X-ray absorption fine structure (EXAFS) and vibrational spectroscopic studies. The XRD data gav
## Abstract The ^295^Pt and ^205^Tl NMR chemical shifts of the complexes [(NC)~5~PtTl(CN)~__n__~]^__n__−^ __n__=0–3, and of the related system [(NC)~5~PtTlPt(CN)~5~]^3−^ have been computationally investigated. It is demonstrated that based on relativistically optimized geometries, by applying an