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Kinetics and mechanism of oxidations by peroxodiphosphate. 6. Copper(II)-catalyzed oxidation of iodide

โœ Scribed by Bharadwaj, Lalit Mohan; Sharma, Devendra Nath; Gupta, Yugul Kishore


Book ID
127316889
Publisher
American Chemical Society
Year
1978
Tongue
English
Weight
482 KB
Volume
17
Category
Article
ISSN
0020-1669

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Kinetics and mechanism of silver(I) cata
โœ P. Parasher; J. Hussain; P. D. Sharma ๐Ÿ“‚ Article ๐Ÿ“… 1991 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 471 KB

A kinetic study of the silver(1)-catalyzed oxidation of tris(1,lO-phenanthroline)iron(II) with peroxodiphosphate was carried out by estimating tris-complex at 510 nm. The reaction is found to conform to the rate law (i). with K2 and K3 being the acid dissociation constants of H~P208-and H~Pz082-, r