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Kinetics and mechanism of oxidation ofcis-diaquabis(glycinato)chromium(III) by periodate ion in aqueous solutions

โœ Scribed by Ismat H. Ali, Yousif Sulfab


Book ID
120783504
Publisher
Springer
Year
2012
Tongue
English
Weight
357 KB
Volume
38
Category
Article
ISSN
0340-4285

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One-step, two-electron oxidation of cis-
โœ Ismat H. Ali; Yousif Sulfab ๐Ÿ“‚ Article ๐Ÿ“… 2011 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 146 KB

The kinetics of oxidation of cis-[Cr III (phen) 2 (H 2 O) 2 ] 3+ (phen = 1,10-phenanthroline) by IO - 4 has been studied in aqueous acidic solutions. In the presence of a vast excess of [IO - 4 ], the reaction is first order in the chromium(III) complex concentration. The pseudo-firstorder rate cons