## Abstract The oxidative cleavage of some aliphatic ketoximes by thallium(III) acetate was studied in the temperature range of 20β40Β°C. The reactions were followed by determination of the rates of disappearance of thallium(III) acetate for variations in [substrate], [Tl(III)], [H^+^], ionic streng
Kinetics and mechanism of oxidation of some aliphatic amines by ditelluratocuprate(III)
β Scribed by C. P. Murthy; B. Sethuram; T. Navaneeth Rao
- Publisher
- Springer Vienna
- Year
- 1982
- Tongue
- English
- Weight
- 335 KB
- Volume
- 113
- Category
- Article
- ISSN
- 0026-9247
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
The kinetics of the oxidation of aliphatic aldehydes, formaldehyde, acetaldehyde, propionaldehyde, n-butyraldehyde, and trichloroacetaldehyde by Peroxomonosulphate (PMS) was carried out in aqueous perchloric acid medium (0.1-1 M H+) a t constant ionic strength of 1.2 M in the temperature range 1O"-6
## Abstract The kinetics of oxidation of methyl, ethyl, __n__βpropyl, isopropyl, and __n__βbutyl acetates to acetic acid and the corresponding aldehyde by the title oxidant in aqueous HCl medium at 40Β°C has been studied. The reaction shows firstβorder with respect to [oxidant] and fractional orders
The kinetics of oxidation of aliphatic amines viz., ethylamine, n-butylamine, isopropylamine (primary amines), diethylamine (secondary amine), and triethylamine (tertiary amine) by chloramine-T have been studied in NaOH medium catalyzed by osmium(W1) and in perchloric acid medium with ruthenium(II1)
## Abstract The kinetics of oxidation of ethylene glycol and 1,3βbutylene glycol by dihydroxydiperiodatoargentate(III) in alkaline medium have been studied by spectrophotometry in the range of 298.2β318.2 K. It is shown that the reaction was first order with respect to each reductant and Ag(III), a