Kinetics and mechanism of oxidation of iso-propyl mandelate by manganese(III) pyrophosphate
β Scribed by R.K. Malkani; K.S. Suresh; G.V. Bakore
- Book ID
- 115975024
- Publisher
- Elsevier Science
- Year
- 1977
- Weight
- 271 KB
- Volume
- 39
- Category
- Article
- ISSN
- 0022-1902
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π SIMILAR VOLUMES
Mn m is stabilized by pyrophosphate in weakly acidic solutions. The nature of the complex formed was elucidated spectrophotometrically. The kinetics of Mn m oxidation of thiocyanate in pyrophosphate medium was investigated over the pH range 2-3. The oxidation followed first order kinetics with [Mnm]
Kinetics of manganese(II1) oxidation of L-arginine has been studied in the presence of pyrophosphate and acetate ions in acidic media at 328 K and 323 K, respectively. The nature of the oxidizing species formed in manganese(II1) solutions was determined by spectrophotometric and redox potential meas