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Kinetics and Mechanism of Oxidation of Dimethyl Sulfoxide with Benzoyl Peroxide in Superbasic Media

✍ Scribed by A. S. Lyavinets; N. T. Marushchak

Book ID: 111608644
Publisher: Springer
Year: 2004
Tongue: English
Weight: 63 KB
Volume: 74
Category: Article
ISSN: 1070-3632
DOI: 10.1023/b:rugc.0000042424.78088.7f

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📜 SIMILAR VOLUMES

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## Abstract The reactions of methyl and methylperoxyl radicals derived from dimethyl sulfoxide (DMSO) with hydrogen peroxide, peroxymonocarbonate (HCO~4~^−^), and persulfate were studied. The major reaction observed for the hydroperoxides was the abstraction of the hydrogen atom by the radicals. Th

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The kinetics of dimethyl sulfoxide (DMSO) oxidation by peroxomonophosphoric acid (PMPA) in aqueous medium a t 308 K and I = 0.4 mol/dm3 follow the rate expressions In the pH range from 0 to 2, where k l and kz are 5.092 X 10-1 dm3/mol sec and = 0, respectively; in the pH range from 4 to 7, where k2