## Abstract The oxidation of inositol by quinquevalent vandadium in acid medium is a firstβorder reaction both in vanadium (V) and inositol. The stoichiometry of the reaction is consistent with the use of two equivalents of vanadium (V) per mole of inositol with the formation of one mole of inosose
Kinetics and mechanism of oxidation of acetanilide by quinquevalent vanadium in acid medium
β Scribed by Reeta Gupta
- Publisher
- Springer Vienna
- Year
- 1990
- Tongue
- English
- Weight
- 300 KB
- Volume
- 121
- Category
- Article
- ISSN
- 0026-9247
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## Abstract The kinetics of oxidation of aldosugars and ketosugar by quinquevalent vanadium in binary mixtures of DMSOβwater and acetic acidβwater in sulfuric acid medium have been studied. The reaction is first order in both oxidant and substrate. The effect of acidity on the reaction kinetics has
## Abstract The reaction between benzohydrazide and potassium bromate catalyzed by vanadium(IV) was studied under pseudoβfirstβorder condition keeping large excess of hydrazide concentration over that of the oxidant. The initiation of the reaction occurs through oxidation of the catalyst vanadium(I
The kinetics of oxidation of gallic acid with potassium bromate in the presence of vanadiurn(V) catalyst in aqueous acid medium has been studied under varying conditions. The active species of catalyst and oxidant in the reaction were understood to be HBrO, and VO,+ The autocatalysis exhibited by o