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Kinetics and mechanism of nucleophilic substitution of dichloroarylazopyridinepalladium(II) by pyridine bases

✍ Scribed by Ramkrishna Roy; Tarun Kumar Misra; Chittaranjan Sinha; Ambikesh Mahapatra; Ankan Sanyal

Book ID
110372536
Publisher
Springer
Year
1997
Tongue
English
Weight
451 KB
Volume
22
Category
Article
ISSN
0340-4285

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Nucleophilic substitution reactions of d
Nucleophilic substitution reactions of diethyl 4-nitrophenyl phosphate triester: Kinetics and mechanism
✍ Enrique A. Castro; Daniela Ugarte; M. Fernanda Rojas; Paulina Pavez; JosΓ© G. San πŸ“‚ Article πŸ“… 2011 πŸ› John Wiley and Sons 🌐 English βš– 200 KB

## Abstract The reactions of diethyl 4‐nitrophenyl phosphate (**1**) with a series of nucleophiles: phenoxides, secondary alicyclic (SA) amines, and pyridines are subjected to a kinetic study. Under excess of nucleophile, all the reactions obey pseudo‐first‐order kinetics and are first order in the