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Kinetics and mechanism of ligand substitution reactions of polymer-supported RuCl3NO(SbPh3)2. Evidence for chelation of the anchored complex

✍ Scribed by Sandro Torroni; Giuseppe Innorta; Antonia Foffani; Alberto Modelli; Francesco Scagnolari

Book ID: 108351300
Publisher: Elsevier Science
Year: 1981
Tongue: English
Weight: 551 KB
Volume: 221
Category: Article
ISSN: 0022-328X
DOI: 10.1016/s0022-328x(00)88372-2

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## Abstract The cluster [W~3~S~4~H~3~(dmpe)~3~]^+^ (1) (dmpe=1,2‐bis(dimethylphosphino)ethane) reacts with HX (X=Cl, Br) to form the corresponding [W~3~S~4~X~3~(dmpe)~3~]^+^ (2) complexes, but no reaction is observed when 1 is treated with an excess of halide salts. Kinetic studies indicate that th