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Kinetics and mechanism of ligand substitution reactions of NiL and Ni2L with cyanide ion (L = hexamethylenediaminetetraacetic acid)

✍ Scribed by Radhey M. Naik; Prem C. Nigam


Publisher
Springer
Year
1986
Tongue
English
Weight
482 KB
Volume
11
Category
Article
ISSN
0340-4285

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## Abstract The kinetics and mechanism of substitution reaction of [Ru(CN)~5~H~2~O]^3βˆ’^ anion with two naphthalene‐substituted ligands viz. L^n^ = nitroso‐R‐salt (NRS) and α‐nitroso‐β‐naphthol (Ξ±NΞ²N) have been studied spectrophotometrically by monitoring an increase in absorbance at Ξ»~max~ = 525 nm