Kinetics and mechanism of ligand-promoted decomposition of the Keggin Al13 polymer
β Scribed by Aria Amirbahman; Michael Gfeller; Gerhard Furrer
- Book ID
- 117118639
- Publisher
- Elsevier Science
- Year
- 2000
- Tongue
- English
- Weight
- 199 KB
- Volume
- 64
- Category
- Article
- ISSN
- 0016-7037
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π SIMILAR VOLUMES
The homogeneous gas-phase decomposition kinetics of silane has been investigated using the single-pulse shock tube comparative rate technique (T = 1035-1184Β°K, P ~d = 4000 Torr). The initial reaction of the decomposition SiH4 ! + SiHz + H2 is a unimolecular process in its pressure fall-off regime w
The homogeneous gas-phase thermal decomposition kinetics of germane have been measured in a single-pulse shock tube between 950 and 1060 K at pressures around 4000 torr. The initial decomposition is GeH4 -GeH2 + H2 in its pressure-dependent regime, with log k ~~~~( 4 m ) = 13.83 f 0.78 -50,750 f 357