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Kinetics and mechanism of isocyanate reactions. I. Reactions of Aryl Isocyanates with Alcohols

✍ Scribed by Prof. Dr. Radu Bacaloglu; Dr. Livius Cotarc; Dr. Nicolae Marcu; Dr. Stefan Toulgyi

Publisher: John Wiley and Sons
Year: 1988
Tongue: English
Weight: 384 KB
Volume: 330
Category: Article
ISSN: 1615-4150
DOI: 10.1002/prac.19883300313

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## Abstract Reaction of chloroglyoxime 1 with aryl isocyanates yielded monocarbamates 3, and chlorooxime functional group was unchanged. The 1,3‐cycloaddition of nitrile N‐oxides generated from 3 to methyl methacrylate gave isoxazole derivatives 5. Compounds 5 were also obtained by carbamoylation o