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Kinetics and Mechanism of Hydroxyl Radical and OH-Adduct Radical Reactions with Nitroxides and with Their Hydroxylamines

✍ Scribed by Samuni, Amram; Goldstein, Sara; Russo, Angelo; Mitchell, James B.; Krishna, Murali C.; Neta, Pedatsur


Book ID
126159374
Publisher
American Chemical Society
Year
2002
Tongue
English
Weight
90 KB
Volume
124
Category
Article
ISSN
0002-7863

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The rate constant of the reaction of OH with DMS has been measured relative to OH + ethene in a 420 1 reaction chamber a t 760 torr total pressure and 298 t 3 K in N L + 0, buffer gas using the 254 nm photolysis of H202 as the OH source. In agreement with a recent absolute rate determination of the