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Kinetics and mechanism of hydrolysis of insecticidal O-(methylcarbamoyl)oximes

โœ Scribed by Mrlina, Georges; Calmon, Jean Pierre


Book ID
126465820
Publisher
American Chemical Society
Year
1980
Tongue
English
Weight
588 KB
Volume
28
Category
Article
ISSN
0021-8561

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Hydrolysis of steroid oximes: Mechanism
โœ Richard E. Huettemann; Arvin P. Shroff ๐Ÿ“‚ Article ๐Ÿ“… 1974 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 325 KB

The conversion of 17a-acetoxy-6a-methyl-4-pregnen-3,20-dione 3-oxime to the corresponding diketone in acidic media was found to be a first-order reaction at 37". The effects of incorporating ester groupings at the oxime function or a t the C-17 position and modifications in ring B were also investig