Kinetics and mechanism of hydration of strained bridgehead bicyclic olefins
✍ Scribed by Chiang, Y.; Kresge, A. J.; Wiseman, J. R.
- Book ID
- 127160146
- Publisher
- American Chemical Society
- Year
- 1976
- Tongue
- English
- Weight
- 398 KB
- Volume
- 98
- Category
- Article
- ISSN
- 0002-7863
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## Abstract The addition of water, acetic acid, and hydrogen bromide to the strained bridge‐head olefins bicyclo[3.3.1]‐1(2)‐nonene **(1)**, bicyclo[4.2.1]‐1(8)‐nonene **(2)**, and bicyclo[4.2.1]‐1(2)‐nonene **(3)** gives exclusively the bridgehead alcohols, acetates, and bromides, respectively. Th
## Abstract A convenient synthesis of the strained methylene‐bridged __trans__‐cyclooctenes bicyclo[3.3.1]‐1 (2)‐nonene **(1)**, bicyclo[4.2.1]‐1(8)‐nonene **(2)**, and bicyclo[4.2.1]‐1(2)‐nonene **(3)** by the intramolecular __Wittig__ reaction is described (see __Schemes 1–4__). The (3‐oxocycloal
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