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Kinetics and mechanism of dissociation of copper(II) complexes of biguanide and someN1-substituted biguanides in aqueous acetate buffer media

โœ Scribed by Supriya Guha; Debabrata Banerjea


Publisher
Springer
Year
1991
Tongue
English
Weight
356 KB
Volume
16
Category
Article
ISSN
0340-4285

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The kinetics of the reaction of [Cu(bigH)2] 2+ (bigH = biguanide) with an excess of amino acid (LH), namely glycine or e-alanine, in aqueous solution in the 7.6-9.0 pH range at different temperatures (30-40~ have been followed by stopped-flow spectrophotometry. The ligand replacement process has bee